一 聚苯醚PPE
聚苯醚化學(xué)名稱為聚2,6-二甲基-1,4-苯醚, PPE(Polypheylene ether) 或簡稱PPO( Polyphenylene Oxide)。又稱為聚亞苯基氧化物或聚苯撐醚,是一類耐高溫的熱塑性樹脂。市場上通用的主要為改性的聚苯醚(Modified Polyphenylene Oxide),簡稱MPPO,或者MPPE(Modified Polypheylene ether)。由于習(xí)慣上,對聚苯醚和其改性共混聚合物都稱為PPE(美國叫法)或PPO(日本叫法),本文也采用通俗稱法:以下稱為PPE或PPO。
二、聚苯醚PPE特性 PPE是一種綜合性能優(yōu)良的熱塑性工程塑料,突出的是電絕緣性和耐水性優(yōu)異,尺寸穩(wěn)定性好。
1.介電性能居工程塑料:PPE樹脂分子結(jié)構(gòu)中無強極性基團,電性能穩(wěn)定,可在 廣泛的溫度及頻率范圍內(nèi)保持良好的電性能。其介電常數(shù)和介電損耗角正切是工程塑料中zui
小的,且?guī)缀醪皇軠囟取穸燃邦l率數(shù)的影響。其體積電阻率是工程塑料中zui高的。PPE的優(yōu)異電性能使其廣泛應(yīng)用于生產(chǎn)電器產(chǎn)品,尤其是耐高壓的部件,如彩電的行輸出變壓器( FBT)等。
2.良好的機械性能及熱性能:PPE子鏈中,含有大量的芳香環(huán)結(jié)構(gòu),分子鏈感性較強。
樹脂的機械強度較高,耐蠕變性優(yōu)良,溫度變化影響甚小。PPE具有較高的耐熱性,玻璃化溫度高達211℃,熔點268℃。
本公司 可以免費提供各種材料物性及各種材質(zhì)認證 如:SGS UL MSDS ROHS MDS 等證明 : 通過這些鏈接您能夠訪問供應(yīng)商資料。我們盡量保證 準確數(shù)據(jù)資料; UL 黃卡含有 UL 驗證的易燃性和電氣特性物性說明
3.優(yōu)異的耐水性:PPE為非結(jié)晶性樹脂,在通常的溫度范圍,分子運動少,主鏈中無 大的極性基團,偶極矩不發(fā)生分極,耐水性非常好,是工程塑料中吸水率zui低的品種。在熱水中長時間浸泡其物理性能仍有很少下降。4.阻燃性良好,具有自熄性:PPE的氧指數(shù)29,為自熄材料,而高抗沖擊性聚苯乙烯的氧指數(shù)17為易燃性材料,二者合一是具中等程度的可燃性,制造阻燃等級PPE時,不需要添加鹵素的阻燃劑,加入含磷類阻燃劑即可達到UL94標準,減少對環(huán)境的污染。
5.收縮率低,尺寸穩(wěn)定性好;無毒,密度小。
6.耐介質(zhì)性和耐光性:PPE對酸、堿和洗滌劑等基本不受腐蝕,在受力的情況下,礦 物油及酮類、酯類溶劑會產(chǎn)生應(yīng)力開裂;對有機溶劑如脂肪烴、鹵代脂肪烴和芳香烴等會使之融漲和溶解。PPE弱點是耐光性差,長時間在陽光或熒光燈下使用產(chǎn)生變色,顏色發(fā)黃,原因是紫外線能使芳香醚的鏈結(jié)合分裂所致。而如何改善PPE的耐光性成為一個課題。
三、聚苯醚(PPE)成型工藝
PPE可通過注塑、擠出等工藝加工成各種制品:
1.注塑:柱塞式或螺桿式注塑機都能加工PPE。一般采用螺桿式注塑機,要求長徑比大于15:1,壓縮比1.7 ~4.0(一般采用2.5~3.5)。
2.擠出:PPE能在擠出機上加工成管、片、棒、塊等。采用排氣式、長徑比大的擠出機。
Iupiace® AH40 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH50 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH60 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH70 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH80 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH8P | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AH91 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AHF6005 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AHF6010 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AHF6010B | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AHF6015 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AN70 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AN80 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AP4 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AP4GM6 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AP6GM2 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AP6GM4 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® AV90 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® EHM1000 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® EHM100R | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® EHM1010A | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® EHM103R | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GAV2010 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GAV2515 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GH10 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GH20 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GH30 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GHF3005 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GHF3010 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GHF3015 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GN10 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GN15 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GN30 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GV10 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GV15 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GV20 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GV30 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GX1050 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GX1100 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® GX1210 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® HGX410N | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® HGX420N | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LGX420N | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LN23 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LN30 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LN40 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LN60 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LN91 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LV40 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® LV60 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® NX-9000 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® TH620 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® TX403 | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® TX903B | Mitsubishi Engineering-Plastics Corp | PPE | |
Iupiace® VSG635V | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® BX503A-1 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® BX504D | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® BX505 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® BX528A-3 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® C61HL | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® C82HL | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® NX7000 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® NXG7201 8240 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® PX603 | Mitsubishi Engineering-Plastics Corp | PPE | |
LEMALLOY® PX603Y | Mitsubishi Engineering-Plastics Corp | PPE |
產(chǎn)品說明 | ||||
Modified polyphenylene ether (PPE), heat resistant, glass fiber-reinforced, suitable for plastic/rubber composites manufactured by the K&K process VESTORAN is the registered trademark of Evonik Degussa GmbH for molding compounds containing poly-2,6-dimethyl-1,4-phenylene ether as polymeric constituent (polyphenylene ether, PPE, also referred to as PPO). As a material of amorphous structure VESTORAN 1900GF20 shows very small mold, shrinkage. Therefore molded parts have a very low tendency to warp. Moldings of VESTORAN 1900GF20 are dimensionally stable and hydrolysis resistant even in hot water, but are more sensitive to organic solvents than semi-crystalline plastics. VESTORAN 1900GF20 is resistant to aqueous alkalines and acides, certain alcohols, and glycol solutions. Glass fiber reinforcement of this molding material combines outstanding heat deflection temperature under load with high strength and rigidity. The even smaller shrinkage compared to non-reinforced VESTORAN depends on the orientation of the glass fibers in the molded parts. VESTORAN 1900GF20 is particularly suitable for the adhesion promoter-free manufacturing of plastic/rubber composites by the Evonik Degussa GmbH-patented K&K process. Compared to VESTORAN 1900, VESTORAN 1900GF20 offers higher rigidity and strength. Colored material contains only cadmiumfree pigments. | ||||
總體 | ||||
材料狀態(tài) |
| |||
資料 1 |
| |||
UL 黃卡 2 |
| |||
搜索 UL 黃卡 |
| |||
供貨地區(qū) |
| |||
填料/增強材料 |
| |||
性能特點 |
| |||
形式 |
| |||
加工方法 |
|
物理性能 | 額定值 | 單位制 | 測試方法 |
密度 | 1.19 | g/cm3 | ISO 1183 |
溶化體積流率(MVR) (300°C/21.6 kg) | 0.915 | in3/10min | ISO 1133 |
收縮率 3 | ISO 294-4 | ||
橫向流量 | 0.60 | % | |
流量: 176°F, 0.0787 in | 0.50 | % |
機械性能 | 額定值 | 單位制 | 測試方法 |
拉伸模量 | 812000 | psi | ISO 527-2 |
拉伸應(yīng)力 (斷裂) | 16000 | psi | ISO 527-2 |
拉伸應(yīng)變 (斷裂) | 3.0 | % | ISO 527-2 |
彎曲模量 | 827000 | psi | ISO 178 |
沖擊性能 | 額定值 | 單位制 | 測試方法 |
簡支梁缺口沖擊強度 | ISO 179/1eA | ||
-22°F, *斷裂 | 5.7 | ft·lb/in2 | |
32°F, *斷裂 | 5.7 | ft·lb/in2 | |
73°F, *斷裂 | 5.7 | ft·lb/in2 | |
簡支梁缺口沖擊強度 | ISO 179/1eU | ||
-22°F, *斷裂 | 24 | ft·lb/in2 | |
32°F, *斷裂 | 24 | ft·lb/in2 | |
73°F, *斷裂 | 24 | ft·lb/in2 |
熱性能 | 額定值 | 單位制 | 測試方法 |
熱變形溫度 | |||
66 psi, 未退火 | 374 | °F | ISO 75-2/B |
264 psi, 未退火 | 365 | °F | ISO 75-2/A |
維卡軟化溫度 | |||
-- | 392 | °F | ISO 306/A |
-- | 374 | °F | ISO 306/B |
電氣性能 | 額定值 | 單位制 | 測試方法 |
表面電阻率 4 | 1.0E+13 | ohm | IEC 60093 |
體積電阻率 | 1.0E+13 | ohm·cm | IEC 60093 |
耐電強度 | 840 | V/mil | IEC 60243-1 |
相對電容率 | IEC 60250 | ||
100 Hz | 2.90 | ||
1 MHz | 2.70 | ||
耗散因數(shù) | IEC 60250 | ||
100 Hz | 0.00080 | ||
1 MHz | 0.0018 | ||
漏電起痕指數(shù) | IEC 60112 | ||
解決方案 A 5 | 175 | V | |
解決方案 A | 200 | V | |
可燃性 | 額定值 | 單位制 | 測試方法 |
UL 阻燃等級 | UL 94 | ||
0.0315 in | HB | ||
0.0630 in | HB | ||
極限氧指數(shù) | 29 | % | ISO 4589-2 |
補充信息 | 額定值 | 單位制 | 測試方法 |
Electrolytical Corrosion - Step | A1 | IEC 60426 | |
Relative Weld Line Strength | 60 | % | ISO 527 |
注射 | 額定值 | 單位制 | |
干燥溫度 | 176 到 230 | °F | |
干燥時間 | < 2.0 | hr | |
螺筒后部溫度 | 536 | °F | |
螺筒中部溫度 | 572 | °F | |
螺筒前部溫度 | 608 | °F | |
射嘴溫度 | 608 | °F | |
加工(熔體)溫度 | 590 到 644 | °F | |
模具溫度 | 257 | °F | |
注塑溫度 | 11600 到 23200 | psi | |
背壓 | 72.5 到 145 | psi | |
螺桿長徑比 | 20.0:1.0 | ||
螺桿壓縮比 | 2.0 : 1.0 到 3.0 : 1.0 | ||
排氣孔深度 | 0.0020 | in | |
注射說明 | |||
Nozzle: Diameter min. 3 mm Holding pressure: 50 to 80% of injection pressure Hydraulic back pressure: 5 to 10 bar, no decompression (specific back pressure 50 to 100 bar) |
:何生
:86-
傳真號碼:86-
地址:廣東 東莞市
聚苯醚 :PPE, 德國贏創(chuàng)德固賽,1900GF20其它產(chǎn)品
聚苯醚 :PPE,南通星辰, LXS109
聚苯醚 :PPE, 德國贏創(chuàng)德固賽,X7342
聚苯醚 :PPE, 德國贏創(chuàng)德固賽,1900GF20
聚苯醚 :PPE, 德國贏創(chuàng)德固賽,1900
聚苯醚 :PPE,日本三菱工程,PX603Y
聚苯醚 :PPE,日本三菱工程,PX603
聚苯醚 :PPE,日本三菱工程,NXG7201 8240
聚苯醚 :PPE,日本三菱工程, NX7000
聚苯醚 :PPE,日本三菱工程,C82HL
聚苯醚 :PPE,日本三菱工程, C61HL